2 Ideal Chain Models

Here we consider ideal chains, that like ideal gases, feature no net interaction (repulsive or attractive) among the n monomers, each with bond length l. We start with a description of the end to end distance of the chain. Given the random nature of displacements of monomers with respect to each other, the mean end-end distance, < R >= 0. The first non-trivial moment of the distribution of end-end distances is the second moment, so we look at the mean squared end-end distance, < R2 >, defined in Equation 3.

⟨R2 ⟩ =   ⟨-R→n.-R→n ⟩
         ⟨( ∑n   ) ( ∑n   ) ⟩
     =         -→ri .(    -→rj)
            i=1       j=1
         ∑n ∑n
     =         ⟨-→ri.-→rj⟩
         i=1 j=1
          ∑n ∑n
     =   l2       ⟨cosθij⟩                                  (3)
           i=1 j=1

 2.1 Freely Jointed Chain
  2.1.1 Equivalent Freely Jointed Chain
 2.2 Freely Rotating Chain
  2.2.1 Worm-Like Chain Model
 2.3 Hindered Rotation Chain
 2.4 Rotational Isomeric States
  2.4.1 The Ising Chain