Soft Matter Lab
Prof. Eric Dufresne - Yale University

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Our research focuses on understanding, controlling and exploiting the properties of soft materials.

At the macroscale, soft matter exhibits a mixture of fluid and solid properties, while at the microscale its structure and dynamics are dominated by thermal fluctuations. Our laboratory manipulates soft materials from the bottom up by altering the interactions of their components and from the top down by applying optical forces.


A brief description of a few of our projects follows...


Colloidal Interactions

The forces between colloidal particles play a crucial role in determining the structure and stability of suspensions, and therefore their response to optical, mechanical and electromagnetic stimuli.   We're developing new ways to measure and manipulate these forces.  In nonpolar environments, we're exploring methods to control electrostatic forces.  In aqueous environments, we're exploiting the properties of biological molecules to create novel interactions


Micro-Opto-Mechanical Systems (MOMS)

We manipulate individual colloidal particles using optical forces.  An single optical tweezer can trap a micron-sized particle near the focal point of a laser beam.  We have developed holographic methods to manipulate hundreds of particles simultaneously.  Each particle can be independently and dynamically moved in 3D.  We're developing new applications for this powerful tool in the physical and biological sciences.

Complex Fluids in Microchannels

Suspensions may flow through microchannels very differently than they do through macroscale devices.  For example, the effective viscosity of blood in the microcirculation may be less than half the bulk viscosity.  Indeed, micro-scale flow may be non-Newtonian in regimes where bulk rheology is linear and Newtonian.  Mechanisms such as geometric confinement, Brownian motion, particle/particle interactions and  particle/wall interactions can all play important roles.  We are interested in understanding the behavior of both model hard- and soft-sphere systems as well as real biological suspensions.  Using both high-speed and confocal microscopy, we investigate the flow of these suspensions through microfluidic channels.  We reconstruct the flow in 3D to analyze its structure and dynamics.  More...,

Plasmonics

Nanoscale metallic structures exhibit suprising optical phenomena.  By coupling photons to surface resonanances (surface plasmon-polaritons),  metallic nanowires can guide and redirect light can over tens of microns.   We are investigating the fundamental physics of this phenomenon and exploring potential applications to integrated nanophotonic devices.


Mechanics of Drying Suspensions

Drying suspensions can fracture and buckle like elastic solids - even when the concentration of solid particles is vanishingly small. The basic physics of these instabilities are relatively well-understood for elastic materials. However, drying suspensions can be viscoelastic: depending on the experimental timescale, they can either store energy in elastic deformation or relieve stress through viscous flow. In addition, the kinetics of drying drives suspensions far from equilibrium, leading to dramatic changes in material properties as solvent evaporates.  We're trying to understand the interplay of forces, structure and kinetics that causes colloidal fluids to jam, buckle and crack.  We're exploring applications to spray-dried powders, coatings and ceramics.

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Copyright Eric R. Dufresne, Yale University, 2004-7