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Complex fluids and granular matter are commonly found in nature (e.g., milk, cytoplasm, groundwater, sand) and in industry (powders, paints, drug delivery systems, cosmetic products). A better understanding of nonequilibrium behavior of these systems is thus important for applications that include design of new microstructured materials, development of new particle segregation methods, and control of particulate flows. Moreover, investigations of their nonequilibrium behavior pose many exciting and challenging fundamental theoretical problems. Examples of microstructural features with important dynamic consequences include shapes and ordering of drops or bubbles in emulsions and foams, conformation of macromolecules in polymeric solutions, and correlations between particles in colloidal suspensions. Due to a relatively large lengthscale and long relaxation time, the microstructure can be substantially distorted even by a weak applied stress. Thus, complex fluids and granular media are often termed "soft condensed matter." Under flow conditions, complex fluids may undergo shear thinning (i.e., a decrease of viscosity with increasing shear rate) due to alignment of the microstructure with the flow. At higher shear rates, the same fluid may exhibit shear thickening due to jamming of particle clusters. Jamming is also responsible for slow relaxation timescales in glassy materials, and is important in the flow of granular matter. For complex fluids confined in channels or pores (e.g., in microfluidic devices), additional complexity arises due to microstructural changes induced by the confinement.
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Text updated: 8/17/05